OP here. I don't think he has them, at least not in the movies, but given that everything else about him is super human and that it got rid of his asthma, astigmatism, etc, it seems plausible? Probably not near Daredevil's abilities, but perhaps more sensitive than normal. It's really just for the sake of the prompt. Maybe Cap could just recognize his mouth...
Re: Captain America thinks he knows Daredevil's identity, but how is it possible?